3. The thermal effect of the reaction Pb + Hg2Cl2 = PbCl2 + 2Hg is -95019 J at 25 C. The EMF of an element operating due to this reaction increases by 0.000145 V with an increase in temperature by 1 C. Determine the EMF of the element and the change in entropy at 25 C; provide a conventional form for writing the element.

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